17.07.2011
At equilibrium, molecules move from the liquid to the gas phase at the same rate as they return to the liquid from the gas phase. In liquids that are mixtures of chemicals, each component vaporizes (evaporates) at its own characteristic rate. The partial pressure of a chemical in a mixture is a measure of the concentration of that chemical’s gas-phase molecules in the air directly in contact with the liquid. In most actual cases equilibrium is not reached so the partial pressure represents the limiting value for chemical concentration in the air.

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